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Basicity of Amides, Imines and Cyanides | IIT JEE Mains Question Solved | Venus Academy | C4-p8/8 - Videos

By Rohit Manglik - 6 years ago

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Venus Academy says:

August 4, 2018 at 9:53 am

Aliphatic Amines - pKb - 1 to 5 (more basic)
Aromatic Amines - pKb - 10
Amides - pKb - 15 (~neutral)
Imines - pKb - 20 (not basic)
Cyanides - pKb - 24 (not basic)

Aliphatic Amine pKb Basicity Piperidine 3.00 More basic
Diisopropylethylamine (DIPEA; Huenig’s base) 3.02
Triethylamine (TEA; Et3N) 3.25 Dimethylamine 3.29
Diisopropylamine (DIPA) 3.43
Trimethylamine 4.19 Less basic